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You receive following error while fetching free Busy for another Federated Organization and get following error from Exchange On-perm servers.
[PS] C:\>Test-FederationTrust
RunspaceId : 49c3c312-1a26-4cd8-a14d-59d736458f76
Id : FederationTrustConfiguration
Type : Success
Message : FederationTrust object in ActiveDirectory is valid.
RunspaceId : 49c3c312-1a26-4cd8-a14d-59d736458f76
Id : FederationMetadata
Type : Error
Message : Unable to retrieve federation metadata from the security token service.
RunspaceId : 49c3c312-1a26-4cd8-a14d-59d736458f76
Id : StsCertificate
Type : Success
Message : Valid certificate referenced by property TokenIssuerCertificate in the FederationTrust object.
RunspaceId : 49c3c312-1a26-4cd8-a14d-59d736458f76
Id : StsPreviousCertificate
Type : Success
Message : Valid certificate referenced by property TokenIssuerPrevCertificate in the FederationTrust object.
RunspaceId : 49c3c312-1a26-4cd8-a14d-59d736458f76
Id : OrganizationCertificate
Type : Success
Message : Valid certificate referenced by property OrgPrivCertificate in the FederationTrust object.
RunspaceId : 49c3c312-1a26-4cd8-a14d-59d736458f76
Id : TokenRequest
Type : Error
Message : Failed to request delegation token.
Resolution:
You need to make sure Exchange On-Prem servers are able to reach MFG i.e there is no as such restrictions.
You need to check if any stale InternetWebProxy attribute is configured at the Exchange servers level.